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Old 11 December 2014, 02:28 AM   #1
mmancari
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1967 5513 lume still glows

I picked this one up today from bonhams nyc. It's a 1967 5513 meters first and the lume still glows. Any one have any information about zinc sulfide which was applied to a batch of dials around this time period?
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Old 11 December 2014, 02:30 AM   #2
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In the dark

In the dark
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Old 11 December 2014, 02:32 AM   #3
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In the dark

Lume
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Old 11 December 2014, 02:45 AM   #4
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Nice pickup & great question

How quickly does it fade?

I have a 68 Omega and a 68 Tudor sub that both glow.
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Old 11 December 2014, 03:00 AM   #5
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Thanks. Haven't had it a day yet. What I first noticed was a difference in hue in natural light from artificial light. I walked in the bathroom and noticed the glow. It fades quickly within minutes. I first questioned the hands as different but they glow and fade at the same rate. I was pleased to find out that it wasn't polished. Even had a bit of dirt in those tight areas. Bracelet is stretched... So be it.
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Old 11 December 2014, 03:17 AM   #6
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It still glows bc back in 66-67 they experimented with a different (in this case trit-zincsulfate) tritium mix. Same with my '67 5512.
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Old 11 December 2014, 03:34 AM   #7
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That thing is in great shape!
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Old 11 December 2014, 03:35 AM   #8
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Quote:
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It still glows bc back in 66-67 they experimented with a different (in this case trit-zincsulfate) tritium mix. Same with my '67 5512.

I've had the same with watches of this era
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Old 11 December 2014, 03:44 AM   #9
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My 5513 and 1675 of the same era also glow and have a beautiful green patina when not in the dark. One of my favorite features of early matte dials.
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Old 11 December 2014, 04:07 AM   #10
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Great! Thanks everyone. Yes , I see that greenish glow. One of the first things I noticed. I wonder how many dials were created with the mixture of zinc. I'm also very fond of the bluish tone of bezel.
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Old 11 December 2014, 04:51 AM   #11
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I'm a bit sceptical (remembering a few big debate threads on TRF on this very topic), 1967 is an awful long time ago considering the half-life of Tritium (with or without zinc). But I am not a nuclear scientist in spite of my nic-name. Peace!
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Old 11 December 2014, 05:04 AM   #12
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I think the question is how long it glows for after being exposed to light and how much will it glow if left in a closed box for a day or so and then checked in a pitch black room.

My 67/68 watches glow quickly, fairly bright, and fade to not useable in less than a minute or two though a little longer - but not useable - in pitch black. That lume is coming from the luminous compounds excited by LED/UV light, not tritium.

My 79 Flake after in a box for a day, and seen in pitch black can barely make out the plots and hands with fully acclimated eyes. That glow is from the luminous compound excited by 3.5 half lifes of Tritium and not usable under any conditions. The compound on the flake has practically zero impact from a UV source (other than a few miniscule bright specs that show)
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Old 11 December 2014, 05:11 AM   #13
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Quote:
Originally Posted by NukeMan View Post
I'm a bit sceptical (remembering a few big debate threads on TRF on this very topic), 1967 is an awful long time ago considering the half-life of Tritium (with or without zinc). But I am not a nuclear scientist in spite of my nic-name. Peace!
I think you've missed the fact that Zinc Sulfide has phosphorescent properties. The time lag of the re-emission of the energy released by the electrons dropping back down the energy levels that were initially raised by specific wavelengths of light being absorbed by the electrons of the compound, allows for a period of "light" emission.

'Scuse any minor innacuracies. The gist is correct, though.
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Old 11 December 2014, 05:17 AM   #14
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I understand the mechanics as you describe it and stand corrected!
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Old 11 December 2014, 10:36 AM   #15
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So I just took some shots with the 1968 Omega SM300 and the 1968 Tudor 7016. Quick hits with the UV LED and go bright and fade fairly quick to not visible in regular light after just a short bit.

I have heard of other tritium dials from this time period with the same result: OP's 5513, 1968 GMTs, etc.





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Old 11 December 2014, 12:31 PM   #16
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Quote:
Originally Posted by NukeMan View Post
I'm a bit sceptical (remembering a few big debate threads on TRF on this very topic), 1967 is an awful long time ago considering the half-life of Tritium (with or without zinc). But I am not a nuclear scientist in spite of my nic-name. Peace!
I have several 5513's from 1967 that also glow briefly. They also both have a slightly green color shift in daylight. This has been discussed at length, nothing to be skeptical about.
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Old 11 December 2014, 04:50 PM   #17
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nice one, congrats - I have a 66 gilt one which also still glows a little
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Old 11 December 2014, 06:29 PM   #18
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Quote:
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nice one, congrats - I have a 66 gilt one which also still glows a little
x2
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Old 11 December 2014, 06:38 PM   #19
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x2
x3

I also once heard from an expert that it's the sulfite in the tritium that does the glowing.
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Old 12 December 2014, 12:50 AM   #20
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btw, nice Seamaster! My '67 SM300 also still glows for a few seconds



Quote:
Originally Posted by linesiders View Post
So I just took some shots with the 1968 Omega SM300 and the 1968 Tudor 7016. Quick hits with the UV LED and go bright and fade fairly quick to not visible in regular light after just a short bit.

I have heard of other tritium dials from this time period with the same result: OP's 5513, 1968 GMTs, etc.





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Old 12 December 2014, 12:52 AM   #21
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Ours could be twins, and guess what...mine glows too!

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Old 12 December 2014, 03:11 AM   #22
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Nice watch David-1675! Great pics linesiders! Love Rolex Forums for its wealth of information.

5 years ago I started getting into watches. I researched every watch, every brand and every nuance. My first love was for vintage rolex. As I gravitated across the board I fell for Panerai. That was very short lived as I saw a crisis within the parent company, Richemont. I've tried on AP diver, nice watch and even considered FP journe (Some day, Its one of my dream watches). Long story short, I made my way back to Vintage Rolex.

When it came down to purchasing this watch, I love it's history, great looking watch, durability and value. Most of all, it fits my personality. I will own this one for a long time!
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Old 12 December 2014, 03:35 AM   #23
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Here is an 1807 that does the same thing:
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Old 12 December 2014, 07:47 AM   #24
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Mine is dead. 5513 of 1983.
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Old 12 December 2014, 07:49 AM   #25
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Quote:
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btw, nice Seamaster! My '67 SM300 also still glows for a few seconds
Gotta love those Big Ts

Quote:
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When it came down to purchasing this watch, I love it's history, great looking watch, durability and value. Most of all, it fits my personality. I will own this one for a long time!
That is a great looking sub - pass on to the great-great-great-grandkids

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Here is an 1807 that does the same thing:
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Old 12 December 2014, 08:06 AM   #26
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Old 12 December 2014, 08:25 AM   #27
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My '66 Sub still glows pretty strong for a little while.
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Old 12 December 2014, 11:08 AM   #28
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Correct for these era dials. Mines glows as well.


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Old 12 December 2014, 11:27 AM   #29
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my glow worm
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Old 12 December 2014, 12:12 PM   #30
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I have a few GMTs from the late 1960s, beginning with serial number 17XXXXX, case back 1967. When I charge the 1967 GMT with a light, the dial and hands glow for a brief period of time. When I charge the other GMTs (dating from 1968 to 1972) with a light, they do not glow at all.
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